As others have said, Conway Hall is pretty much the London home of secularism - they put on recurring talks and events: http://conwayhall.org.uk

London also has a number of Skeptics in the Pub groups who put on evening talks - not always secular, but indeed skeptical/rationalist/fitting in with that worldview: http://www.sohoskeptics.com (Soho) http://london.skepticsinthepub.org (Camden) http://ealing.skepticsinthepub.org/ (Ealing) There's a few others (Hackney, Kingston) that don't have any events presently planned.

In addition next month is London's first Skepticamp at Conway Hall, which will be a day of interesting skeptical talks: http://skepticamp.co.uk

And as mentioned, the Central London Humanists are a lovely group. There's a few other humanist groups in the neighborhood but they, er, tend to have an older demographic...

http://sundayassembly.com/

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